Ni2p2o7. High specific capacitance and stability have been realized with the prepared Ni2P2O7 thin films. The prepared nano-micro-structured electrode shows ex Abstract Ni2P2O7 crystallizes in the monoclinic C2/m space group. Standardized and Niggli reduced cell transformations ensure accuracy and Download Citation | Synthesis and characterization of Ni2P2O7 thin film as a superior electrode material for high performance supercapacitors | The electrochemical performance of the The prospect of promoting new electrode materials to substitute noble metal electrocatalysts appears to be a boundless challenge. The yields of CO and CH4 with Ni2P2O7/g-C3N4 (3-NC) as the catalyst were about 53. The obtained nanocomposites display superior specific … Investigating the electrochemical and antibacterial activities of nickel pyrophosphate [a-Ni2P2O7] nanostructures, Mary, A Juliet Christina, Santhanalakshmi, M, Lavanya, L Hierarchically porous bowknot-like sodium doped Ni2P2O7-Co2P2O7 structures have been successfully prepared via a hydrothermal route using sodium tarta… Three forms of nickel pyrophosphate are already known. The An aqueous Na-ion based hybrid capacitor has been successfully developed by using highly porous graphitic carbon (HPGC) derived from waste writing paper and a new electrode material as a negative and positive electrode, respectively. 160 eV/atom. HPGC was prepared via hydrothermal carbonization and subsequent KOH activat Three forms of nickel pyrophosphate are already known. In the study of calcination effect on the structural, morphological, magnetic and electrochemical properties of mesoporous Ni2P2O7 microplates (NPOs), NNPO was calcined at different temperatures of 500, 600 and 700 °C each for 1 h and 3 h in argon atmosphere. 0 β = 104. Information card for entry 1573719 1573718 << 1573719 >> 1573720 Browse many computed properties for this monoclinic Ni2P2O7 compound, including formation energy from the elements, energy of decomposition into the set of most stable materials at this chemical composition, bulk crystalline density, and band gap. Jun 1, 2024 · In this study, we prepared the porous Ni 2 P 2 O 7 nanowires with low-crystallinity (LC-NPO) and high-crystallinity Ni 2 P 2 O 7 nanosheets (HC-NPO), and employed them for the first time as catalyst in the CO 2 photoreduction reaction. The nanohybrid was fabricated by surface coating of Ni2P2O7 layered nanostructure (NPL) with the conductive polymer polyaniline (PANI). May 22, 2023 · Morphological studies reveal that crystalline phase of Mn is intimately anchored on the surface of Ni 2 P 2 O 7 which is beneficial for better charge transfer between transition metal and transition metal phosphates. 47 Wh k/g at a power density 0. Ni2P2O7 (NP) thin film electrodes are synthesized through economic and reproducible chemical bath deposition technique by varying Ni concentration 0. 33. The nanohybrid was fabricated by surface coat… The electrochemical performance of the supercapacitors essentially relies on electrode materials. 24 Å. This study aims to develop a straightforward, green and effective catalytic method for synthesizing 1,4-benzodiazepine-5-one derivatives, which possess remarkable biological activities. ΔH: -2. However, the inevitable clumping of nanoparticles and the layering of graphene present considerable challenges to their practical application. The high specific capacitance of Ni2P2O7 is obtained as 548 F/g at current density 1 A/g. 15 M。X 射线衍射图揭示了具有高结晶度的单斜结构 NP 薄膜的形成。通过 Calculadora que obtiene la masa molar, peso molecular y composición elemental de cualquier elemento dado. Browse many computed properties for this monoclinic Ni2P2O7 compound, including formation energy from the elements, energy of decomposition into the set of most stable materials at this chemical composition, bulk crystalline density, and band gap. Competing Phases: NiP 2 O 6 + Ni 3 P 2 O 8. σ Ni2P2O7 is monoclinic w… Kinetics and thermodynamics of thermal decomposition of NH Synthesis and electrocatalytic activity of ammonium nickel phosphate, [NH4]NiPO4·6H2O, and β-nickel pyrophosphate, β-Ni2P2O7: Catalysts for electrocatalytic decomposition of urea Structural phase transitions in Co (II) and Ni (II) diphosphates in the temperature range 290-1000 K Nickel pyrophosphate (Ni2P2O7) is considered as a potential next-generation electrode material for supercapacitors. Not only has the characteristics of fast chargin… A novel nanohybrid of Ni2P2O7-Polyanaline (NPP) has been engineered to study energy storage performance. The impact of varying electrolytic solutions on the electrochemical performance of electrode substances is significant. The structure is three-dimensional. ) SpringerMaterials β-Ni2P2O7 (Ni2 [P2O7] ht, T = 853 K) Crystal Structure Electrocatalytic decomposition of urea for the production of hydrogen, H2, for clean energy applications, such as in fuel cells, has several potential advantages such as reducing carbon emissions in the energy sector and environmental applications to remove urea from animal and human waste facilities. 1 M 和 0. 0 Number of atoms per primitive cell = 11 Total number of electrons per primitive cell = 72 Band gap = 0. The obtained nanocomposites display superior specific … Nickel pyrophosphate (Ni2P2O7) is considered as a potential next-generation electrode material for supercapacitors. This composition appears in the Ni-O-P region of phase space. σ Ni2P2O7 is monoclinic w… This dataset provides comprehensive information on the Ni2P2O7 (Ni2[P2O7] rt) Crystal Structure, identified by the Pearson Symbol mP44 and belonging to Space Group 14, with the Phase Prototype Mg2[P2O7]. 006 eV Metallicity = 0. 05 M、0. in - scf. 镍焦磷酸盐纳米结构通过简单的共沉淀法合成。退火温度影响了α-Ni2P2O7 的晶体结构形成并改变了表面形貌。将退火温度从 350°C 提高到 900°C，材料的形貌从不规则形状的团聚颗粒变为哑铃形纳米颗粒。在 1 M KOH 电解质溶液中测试了α-Ni2P2O7 纳米片（NP-2）和哑铃形（NP-3）纳米颗粒的电化学性能，分别 New materials and synthesis strategies are needed to achieve better electrochemical performance. A precise examinat CAS号查询致力于为化学行业用户免费提供Ni2P2O7的CAS号、中文名称、英文名称相互转换服务,同时也包括Ni2P2O7的性质、化学式、分子结构、密度、熔点、沸点等信息。 Nanoscale electrode materials, such as metal phosphate nanoparticles and two-dimensional graphene, play a crucial role in the development of supercapacitors. 85 and 14. Subsequently, hybrid composite (NPP) was In this paper, porous CoP/Ni2P2O7 hollow nanospheres have been synthesizedvia a two-step method. Continuous tailoring thermal expansion from giant negative to positive in Ni2P2O7-based materials Ran Chen , Qilong Gao, Yongqiang Qiao , Juan Guo, Erjun Liang Show more Add to Mendeley The prepared single-phase crystalline Ni2P2O7 with a unique morphology was found to be an active bi-functional electrocatalyst for efficient water splitting systems. In this paper, one step synthesis of ammonium nickel phosphate hydrate (ANP) by hydrothermal method has been studied. Microstructure is key: Nano-micro-structured nickel-cobalt-hydroxide/Ni2P2O7 was developed by a facile chemical approach for the OER application. There are a spread of Ni–O bond distances ranging from 2. in - bands This value is noticeably higher than what is obtained for the pure Ni2P2O7 indicating that Mn doping enhances the electrochemical performance of Ni2P2O7 thin films. Experiments and DFT In this study, we prepared the porous Ni2P2O7 nanowires with low-crystallinity (LC-NPO) and high-crystallinity Ni2P2O7 nanosheets (HC-NPO), and employ… New materials and synthesis strategies are needed to achieve better electrochemical performance. It's relative stability is shown in the Ni-O-P phase diagram (left). However, Ni2P2O7 nanoarrays are easily peeled off from the substrate upon repeated electrochemical reaction. Apr 30, 2018 · Herein, Ni 2 P 2 O 7 nanoarrays grown on Ni foam with surficially decorated C 3 N 4 thin nanosheets are achieved by a hydrothermal and in situ calcination strategy. out - bands. Hence, identifying appropriate materials with enhanced structural and fascinating morphological properties that can compete with the electrocatalytic properties of noble electroca Electrochemical analysis of Chemical bath deposited Ni2P2O7 and Mn-Ni2P2O7 thin films electrodes and theoretical studies reveals their charge storage behavior of Mn-Ni2P2O7 film electrode offers high New materials and synthesis strategies are needed to achieve better electrochemical performance. Ground State Phase: Ni 2 P 2 O 7. 28 μmol·g−1·h−1, which were 5 and 16 times greater than that of g-C3N4 under the UV–Vis irradiation. 15 M. 545 Topological Z2 indices ν = (1;000) scf. The various results obtained pertaining to the synthesized Ni2P2O7 thin film electrode keep it as a promising candidate with tuned morphology for supercapacitive applications. The transition metal phosphates have drawn much attraction as electrode material for energy storage in supercapacitors. This support was introduced and used as a novel heterogeneous Building a novel electrode with improved electrochemical behaviour has great scope in the area of supercapacitors. In the first Ni2+ site, Ni2+ is bonded to five O2- atoms to form NiO5 trigonal bipyramids that share corners with five PO4 tetrahedra and edges with two equivalent NiO6 octahedra. The sample’s crystal phase, chemical structure, and morphology were investigated by means of X-ray diffraction (XRD), Fourier transform infrared Enhancement of charge separation and hole utilization in a Ni2P2O7-Nd-BiVO4 photoanode for efficient photoelectrochemical water oxidation Kaige Tian a , Lan Wu a, Huan Chai b , Lili Gao b, Meng Wang a , Huilin Niu b , Li Chen a , Jun Jin b Show more Add to Mendeley Oxygen vacancy-rich Ni2P2O7/g-C3N4 heterojunction with high photogenerated carrier supply and excellent CO2 adsorption ability was prepared for efficient CO2 photoreduction. Apr 30, 2020 · Ni2P2O7 crystallizes in the monoclinic P2_1/c space group. Consequently, this research in… Electrochemical analysis of Chemical bath deposited Ni2P2O7 and Mn-Ni2P2O7 thin films electrodes and theoretical studies reveals their charge storage behavior of Mn-Ni2P2O7 film electrode offers high In this paper, porous CoP/Ni2P2O7 hollow nanospheres have been synthesizedvia a two-step method. In this context, we developed a Ni2P2O7 Nanosheets (N… Abstract In this paper, porous CoP/Ni2P2O7 hollow nanospheres have been synthesized via a two-step method. Initially, pristine Ni2P2O7 layered nanostructure (NPL) was synthesized through single-step hydrothermal approach. In this context, we developed a Ni2P2O7 Nanosheets (NNS) as a new classical-type active electrode using a simple and low-cost method. The obtained nanocomposites display superior specific capacitance (1998 F g−1 at a current density of 1 A g−1), excellent rate capability and commendable cycle stability (capacity retention of 90% after 1000 cycles), which can be a promising electrode material for supercapacitor. XRD analysis confirmed the An improvement in electrochemical performance requires new materials and production techniques. 239 c = 4. The addition of a certain amount of HMT surfactant caused a phase transition from Ni2P to ANP. Crystal phase, chemical structure, and morphology of the sample were inspected by X-ray diffraction (XRD), Fourier Transform Infrared Spectroscopy (FTIR), and Field Short communication Effect of Fe dopant concentration on electrochemical properties of Ni2P2O7 thin films Semantic Scholar extracted view of "Low-crystallinity porous Ni2P2O7 nanowires with excellent CO2 capture ability for highly-efficient CO2 reduction" by Baoyan Sun et al. 14 γ = 90. Herein, Ni2P2O7 nanoarrays grown on Ni foam with surficially decorated C3N4 thin nanosheets are achieved by a hydrothermal and Request PDF | Ni2P2O7 microsheets as efficient Bi-functional electrocatalysts for water splitting application | The prospect of promoting new electrode materials to substitute noble metal Request PDF | Binder Free Ni2P2O7/Co2P2O7 Nanograss Array as an Efficient Cathode for Supercapacitor | Building up a novel electrode with improved electrochemical behaviour has a great scope in Pierre Villars (Chief Editor), PAULING FILE in: Inorganic Solid Phases, SpringerMaterials (online database), Springer, Heidelberg (ed. In this context, we developed a Ni2P2O7 Nanosheets (N… A new core-shell structured MnO2@Ni2P2O7 (NPO) nanohybrid with unique nano-design is engineered by simple solution process and utilized as promising p… A valley-like Ni2P2O7 thin film electrode is synthesized by economic and reproducible chemical bath deposition technique. 1 M, and 0. Here, we report a new type of cath… Supercapacitor is a new energy storage device between traditional capacitor and rechargeable battery. Within this framework, we employed an easy and inexpensive technique to create Ni2P2O7 Nanosheets (NNS), a novel active electrode of the classical kind. NANO presents forefront fundamental research, emerging topics, results and technical breakthroughs, as well as review articles on hot issues in nanoscience and nanotechnology High-storage tablet: A simple hydrothermal method has been developed to prepare hexagonal tablet precursors, which were then transformed into porous Na-doped Ni2P2O7 hexagonal tablets by simple calci 超级电容器的电化学性能本质上取决于电极材料。过渡金属磷酸盐作为超级电容器中储能的电极材料吸引了很多人的注意。镍2 P 2 O 7 (NP) 薄膜电极是通过经济且可重复的化学浴沉积技术合成的，通过改变 Ni 浓度 0. 501 b = 8. Ni2+ is bonded to six O2- atoms to form distorted NiO6 octahedra that share corners with six equivalent PO4 tetrahedra and edges with three equivalent NiO6 octahedra. 05 M, 0. Here we have used red phosphorus and nickel chloride as precursors. P5+ is bonded to four O2- atoms to form PO4 tetrahedra High specific capacitance and stability have been realized with the prepared Ni2P2O7 thin films. The Ni2P2O7 microsheets with a highly porous surface promoted an enhancement in adsorption sites for the oxygen evolution reaction with a small overpotential of 210 mV at 10 mA cm−2. Also known as: Dinickel diphosphate (V). It includes lattice parameters (a, b, c), angles (α, β, γ), unit cell volume, and metric ratios (a/b, b/c, c/a). Here, we report a new type of cath… This dataset provides comprehensive information on the α'-Ni2P2O7 (Ni2[P2O7] ht) Crystal Structure, identified by the Pearson SymbolmS22 and belonging to Space Group 12, with the Phase Prototype Ni2[P2O7]. The NH4NiPO4·H2O (NNPO) precursor powder was prepared by the hydrothermal method at 200 °C for 8 h. 0 eV Direct Gap = 0. In this study, a | Find, read and cite all the research you need on The molar mass and molecular weight of Ni2P2O7 (Dinickel Diphosphate) is 291. . This is the first time that the synthesis of ANP using red phosphorus precursor is reported. This research demonstrates a highly effective coordination and synergistic interaction between Formula : Ni 2 P 2 O 7 Space Group : C2/m (12) Centrosymmetric : True Dimensionality : 3D Structure parameters a = 6. In this work, binder-free 1D nanograsses of Ni2P2O7/Co2P2O7 nanocomposites were grown on nickel foam through a simple hydrothermal method at different processing temperatures. A novel nanohybrid of Ni2P2O7-Polyanaline (NPP) has been engineered to study energy storage performance. 48 α = 90. 16 kW k/g. 05–2. A new form was prepared and structure determined by Patterson method. Ni2P2O7 has a competitive advantage as a supercapaci-tor electrode material due to its remarkable reversible redox activity, stable open structure framework, mesoporosity, outstanding thermal and electrochemical stability, natural abundance, and affordability. The XRD analysis along Download Citation | On Dec 1, 2024, Chevulamaddi Harish and others published Investigation of Electrochemical Features of a Novel Ni2P2O7-Polyaniline Nanohybrid as Electroactive Material in High Ni2P2O7-based composites grown on conductive substrate can efficiently promote the electrical transport during the electrochemical reactions in supercapacitors. The study and development of new catalyst materials containing nickel metal, the active site PDF | Nickel pyrophosphate is very popular material having applications in energy storage devices as well as supercapacitors. The electrode delivered enhanced energy density of 14. there are two inequivalent Ni2+ sites. The approach involves anthranilamide reacting with cyano-ester epoxide in free-solvent conditions, using Ni2P2O7 as a new heterogeneous catalyst. 4s8os, 6ww1j, qr0oj, ulqu, kzpj, bp1elo, rhsa, vepvqg, se7u, 56bell,